Professional Zinc Alloy Surface Finishing Solutions
Gelatin
Gelatin
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Product description
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Product Overview
Gelatin is a purified protein colloid obtained by controlled hydrolysis of collagen, sold for electroplating as a grain refiner and leveling agent for acid copper and matte tin baths. In the plating tank gelatin does not react like a metal salt: it adsorbs on the growing cathode surface and temporarily slows deposition on peaks and protrusions, so the deposit grows smoother, finer-grained and more uniform. Market grades are the key decision point: technical/photographic grade (low ash, low chloride, low heavy metals, controlled jelly strength) is made for process baths, while edible and food-grade gelatins contain sulfite and other preservatives plus variable jelly strength and must not be used in plating. Cheap or over-aged lots hydrolyze into peptides that cause hazy, streaked deposits. QLQ selects low-ash technical gelatin with a documented jelly strength range and no preservatives for its plating-chemical program.
Product Identity (Encyclopaedia Card)
| Property | Value |
|---|---|
| Chemical name | Gelatin |
| Chemical formula | Protein (glycine-rich polypeptide) |
| CAS number | 9000-70-8 |
| Appearance | Pale yellow to amber granules or powder |
| Grade / type | Industrial / plating grade |
| Standard packing | 25 kg PP woven bag or kraft paper bag with PE inner liner; 25 kg fibre drum |
What it is and what it does. Gelatin is a traditional protein brightener and levelling agent for acid copper, bronze and brass baths, where it refines the grain and improves the throwing power of the deposit.
- Pale yellow to amber granules; dissolved in hot water before addition and dosed by the analysis or the Hull cell.
- Protein brighteners decompose slowly in the bath and their breakdown products also affect the deposit, so the level must be watched.
- Widely used in barrel bronze and brass plating of zipper sliders, where it gives a warm semibright deposit.
Typical Use in a Plating / Finishing Line
| Item | Typical guidance |
|---|---|
| Acid copper / bronze bath | 0.01-0.5 g/L depending on the system |
| Preparation | Dissolve in hot water and add as a dilute solution |
| Control | Hull cell panel appearance plus periodic carbon treatment |
Safety, Handling & Storage
| Item | Requirement |
|---|---|
| Hazard classification | Not classified as dangerous for transport in most cases; observe good industrial hygiene and dust control |
| Personal protective equipment | Dust mask, goggles and gloves for powder handling; general ventilation |
| Spill / first aid | Sweep up dry; material is a nuisance dust — avoid breathing the dust |
| Storage | Cool, dry, sealed store; keep bags closed, off the floor and away from moisture |
| Transport | Classified and packed according to IATA/IMDG for the hazard class; UN number and packing group stated on the shipping documents |
Quality Documents Shipped With Every Batch
| Document | Comment |
|---|---|
| COA (certificate of analysis) | Provided with the shipment; batch traceable to the production date |
| MSDS (safety data sheet) | Provided with the shipment; batch traceable to the production date |
| Packing list | Provided with the shipment; batch traceable to the production date |
| Commercial invoice | Provided with the shipment; batch traceable to the production date |
| Certificate of origin on request | Provided with the shipment; batch traceable to the production date |
Buyer Questions We Answer Every Week
| Question | Answer |
|---|---|
| Why does the deposit lose brightness over time? | Protein breakdown products accumulate; a regular activated carbon treatment removes them. |
| Can gelatin be replaced by a modern brightener? | Yes, but the substrate colour and the grain structure differ; a trial is needed. |
| Item | Typical Value |
|---|---|
| Appearance | Light yellow to tan powder / granules, free-flowing |
| Type | Technical / photographic grade, preservative-free |
| Jelly strength (Bloom) | 150-250 g (lot-certified) |
| pH (1% solution) | 4.5-7.0 |
| Moisture | ≤ 14% |
| Ash | ≤ 2.0% |
| Chloride | ≤ 0.1% (low-chloride lot) |
| Heavy metals (as Pb) | ≤ 10 ppm |
| Standard packing | 25KG/BAG, kraft bag with PE liner |
How It Works in the Bath (Dose-Response)
Gelatin molecules are long-chain proteins that diffuse to the cathode and adsorb preferentially where the current density is highest - exactly where a deposit would otherwise grow fastest and roughest. The adsorbed film raises the activation energy for metal deposition at those points, letting low-current areas catch up. The result is a smoother, denser, finer-grained deposit. Because the effect is physical adsorption, gelatin is consumed continuously and its breakdown products accumulate, which makes it a classic “little and often” additive:
| Gelatin in bath | Effect on acid copper deposit |
|---|---|
| 0 g/L | Coarse, columnar grain; roughness at edges; dull finish |
| 0.05-0.2 g/L (normal) | Fine grain, good leveling, smooth semi-bright deposit |
| 0.3-0.5 g/L | Leveling plateaus; risk of haze and pinholes rises |
| > 0.5 g/L (over-dosed) | Brittle, pitted deposit; low-current areas turn milky gray |
In matte tin plating the working range is higher (1-2 g/L, usually with β-naphthol) because the sulfate tin bath operates at higher temperature and consumes the colloid faster. Typical gelatin consumption in a decorative acid copper line is 2-5 g per 1000 Ah; top up in small doses after a Hull cell check rather than on a fixed calendar.
Typical Bath Formulations (Working Ranges)
| Component | Acid Copper (decorative) | Acid Tin (matte) |
|---|---|---|
| Copper sulfate pentahydrate | 180-240 g/L | - |
| Sulfuric acid | 55-75 g/L | 80-120 g/L |
| Chloride (as HCl) | 40-80 mg/L | - |
| Tin (as SnSO4) | - | 25-40 g/L |
| Gelatin | 0.05-0.2 g/L | 1-2 g/L |
| β-Naphthol | - | 0.5-1.0 g/L |
| Temperature | 22-32°C | 20-35°C |
| Cathode current density | 2-5 A/dm² (with agitation) | 0.5-2 A/dm² |
These are workshop-proven starting ranges for zipper and hardware lines; fine-tune 10-20% for water quality and loading ratio. Gelatin alone gives a semi-bright copper; where mirror copper is required it is combined with proprietary levelers or used as a backup leveler in formulations.
Quality Checks Before Use
| Check | Method | Pass |
|---|---|---|
| Appearance & odor | Visual against retained sample | Uniform tan color; mild protein smell, no rancid/fishy note |
| Solubility | Swell 10 g in cold water 30 min, then heat to 50°C | Clear amber solution, no undissolved specks, no surface scum |
| Ash / chloride | COA review | Ash ≤ 2%, chloride ≤ 0.1% (high chloride corrodes anodes) |
| Hull cell compare | Add 0.1 g/L to a fresh acid copper panel vs reference | Smoothing appears without haze or pits at high CD |
How QLQ controls it: every incoming gelatin lot is quarantined until the COA (Bloom value, ash, chloride, heavy metals) is checked and a Hull cell panel is run in a live acid copper bath. Because one high-ash or sulfite-preserved lot can contaminate an entire copper line, each shipped batch is traceable by number and a retained sample is kept for 12 months for re-testing.
Common Problems & Fixes (Workshop Table)
| Problem | Root cause | Fix |
|---|---|---|
| Rough, coarse deposit at edges | Gelatin exhausted or never added | Hull cell first, then top up 0.05 g/L increments |
| Milky haze in recesses | Over-dosed or aged breakdown peptides | Carbon treat 2-4 g/L, re-make additive, re-polish panel |
| Pinholes / pitting | Too much colloid; poor wetting; hydrogen bubbles stuck | Cut dose; add wetting agent; check air/mechanical agitation |
| Cloudy, lumpy make-up | Powder added to hot water directly | Always pre-swell in cold water, dissolve below 55°C |
| Bath smells, panels get streaky in summer | Protein stock solution spoiled (bacteria) | Make stock fresh weekly; keep stock cool; carbon treat tank |
| Bright range narrows suddenly | Wrong gelatin grade used (edible lot with sulfite) | Dump the dose, carbon treat, switch to technical grade |
Handling & Safety
- Health: gelatin is an animal protein powder; wear a dust mask and gloves when weighing. Dust can irritate the respiratory tract and protein is a sensitizer for some people.
- Dissolving: pre-swell in cold or lukewarm water for 20-30 minutes, then warm gently to 45-55°C with stirring. Never boil - heat above 60°C degrades the colloid and destroys its leveling power.
- Stock hygiene: aqueous gelatin stock supports bacteria and fungi, especially in tropical weather. Prepare small weekly volumes and store refrigerated or in a cool place; discard if it turns cloudy or smells.
- Storage: keep bags sealed in a cool, dry store. Heat and humidity accelerate hydrolysis; a lot older than 12 months should be Hull-cell re-verified before use.
- Waste: gelatin is biodegradable and adds only organic load; it does not complicate metal-bearing effluent treatment, but carbon-treatment sludge is still hazardous because of adsorbed metals.
What It Does on Iron, Zinc Alloy, Copper and Stainless Steel Parts
| Substrate | Role of the gelatin-refined deposit | Practice note |
|---|---|---|
| Iron / steel hardware | Fine-grained copper underlayer levels scratches and gives nickel a smooth base; gelatin cost-effectively controls copper grain on struck parts | Acid copper only after a thin strike (or Wood’s-type activation); never plate acid copper directly on passive steel |
| Zinc alloy (sliders, buckles) | Gelatin-refined acid copper improves the buffed appearance after a protective copper base; supports the Cu-Ni-Cr CASS stack | Zinc dissolves in acid copper - always cover with pyrophosphate or cyanide copper first, then acid copper |
| Copper / brass | Direct plating works well: gelatin levels the surface and tightens grain for the white nickel finish that follows | Activate in 3-5% sulfuric acid; keep gelatin at 0.05-0.15 g/L for barrel work |
| Stainless steel | In nickel-strike-then-copper routes, gelatin copper deposits a ductile layer that resists peeling during later forming | Strike nickel at high CD first; low gelatin dose keeps ductility high |
FAQ
| Question | Answer |
|---|---|
| Can I use supermarket (food) gelatin to save money? | No. Food grades contain sulfite and other preservatives that poison acid copper and tin baths, and their jelly strength varies wildly between batches. The bath-treatment cost will exceed any saving. |
| How do I dose gelatin correctly? | Start from the Hull cell: add 0.05 g/L steps until the high-current edge smooths without haze, then keep a log and top up in small doses as the panel drifts. |
| I over-dosed. How do I remove excess gelatin? | Activated carbon treatment (2-4 g/L powder, 50-60°C, 1-2 h with agitation), then filter and rebuild the additive by Hull cell. Electrolytic dummying alone removes colloid too slowly. |
| Does QLQ help with the rest of the copper-nickel system? | Yes. Gelatin ships with a COA, and QLQ engineers help balance it against copper brighteners, wetting agents and the nickel baths that follow - remotely or during line commissioning. |
Copper deposit rough or hazy? Send Hull cell photos to QLQ engineering - we diagnose additive balance for plating customers in 10+ countries. Contact us.
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Specifying Gelatin for your line
Send the four details below and we confirm fit, packing and price the same working day.
- Application: which tank or process it serves.
- Dimensions or capacity: drawing preferred.
- Material: where it contacts chemicals or heat.
- Quantity: first order and expected annual use.
| What you send | What you get back |
|---|---|
| Part drawing or sample | Compatibility check and recommended settings |
| Output target per shift | Capacity, tank or rack count, manpower |
| Finish spec with tolerance | Control points and acceptance tests |
| Site conditions (power, water, space) | Layout proposal and utility requirements |
Buying questions we answer most
What is the minimum order quantity?
One carton or one unit for most items. Trial quantities are quoted separately from production volumes.
Can it be customised?
Dimensions, material and surface treatment can be adapted. Send a drawing or a sample and we confirm what changes and what stays standard.
What is the lead time?
Stock items ship within a week of confirmation; made-to-order items typically 20-35 days.
What documentation comes with the shipment?
Packing list, material certificate where applicable, and export documents prepared per destination.
Put Gelatin into a process
- Process overview - how each stage connects
- Plating workshop - rack and barrel line layout
- Painting workshop - spray, cure and colour control
- Product overview - what else the line needs